Collision frequency of Lennard-Jones fluids at high densities by equilibrium molecular dynamics simulation

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United Nations Educational, Scientific and Cultural Organization and International Atomic Energy Agency THE ABDUS SALAM INTERNATIONAL CENTRE FOR THEORETICAL PHYSICS COLLISION FREQUENCY OF LENNARD-JONES FLUIDS AT HIGH DENSITIES BY EQUILIBRIUM MOLECULAR DYNAMICS SIMULATION

Arising from the inability of theoretical calculations to give accurate descriptions of (shear) viscosity in rare gases at high densities, we investigated the likely cause of discrepancy between theory and experiments. Molecular Dynamics simulations were performed to calculate transport coefficents and collision frequency of rare gases at high densities and different temperatures using a Lennar...

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Collision dynamics of nanoscale Lennard-Jones clusters

An investigation of collision dynamics of nanoparticles for a broad range of impact factors and collision speeds is presented. The investigation is based on molecular dynamics simulations in conjunction with the Lennard-Jones interaction potential thus making the results applicable for a broad range of material properties. Identification criteria are used to classify the collision dynamics into...

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Crystal Growth of the Lennard-Jones (100) Surface by Means of Equilibrium and Nonequilibrium Molecular Dynamics

On the basis of Onsager’s hypothesis a new method is presented to calculate growth rate constants of various crystal faces from the fluctuations of interfaces during NVT simulations. The method is applied to the (100) face of a Lennard-Jones crystal grown from the melt. The results are in perfect agreement with those obtained by means of NPT nonequilibrium simulations. The new method allows for...

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Phase diagrams of Lennard-Jones fluids

Smit and Frenkel’ have shown that the phase diagram of the two-dimensional Lennard-Jones fluid depends largely on the details of the truncation of the potential. In this Note, Gibbs-ensemble calculations are reported for the three-dimensional Lennard-Jones fluid. As expected, the phase diagram for this system also depends significantly on the details of the truncation. The Lennard-Jones potenti...

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Solvation pressure in a Lennard-Jones fluid by molecular dynamics simulation

We present molecular dynamics simulations of a simple dimer immersed in a Lennard-Jones LJ fluid to test the validity of the solvation pressure model in a system where we attempt to isolate the general and ubiquitous solvation pressure. The solvated dimer acts as a simple pressure gauge in a system where the cohesive energy density CED of the solvent is fixed. We study the dimer bond length as ...

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ژورنال

عنوان ژورنال: Pramana

سال: 2010

ISSN: 0304-4289,0973-7111

DOI: 10.1007/s12043-010-0136-2